A new process of synthesizing 3,5-dimethylaniline with 3,5-dimethylphenol and gaseous ammonia by vapor-solid phase amination was developed. The catalyst was selected and the preparation of catalyst was discussed.

本文分析了3,5-二甲基苯酚气固相氨基化制3,5-二甲基苯胺的国内外研究现状，自行组装了一套气固相积分反应装置，开发出以3,5-二甲基苯酚、氨气为原料，气固相氨基化合成3,5-二甲基苯胺的新工艺路线，筛选出了该反应体系的催化剂。

Recent reports of Cu(I)-catalyzed intermolecular C-N coupling reaction enticed us to search for a new method of Cu(I)-catalyzed intramolecular amination reaction for the synthesis of indolo1,2-bindazole structures.

近年来,铜催化的碳-氮键偶联氨基化反应被广泛报道,这激发了本课题组探索经铜催化的分子内氨基化反应来合成吲哚并1,2-b吲哒唑类化合物的兴趣。